فهرست مطالب

Global Journal of Environmental Science and Management
Volume:9 Issue: 4, Autumn 2023

  • تاریخ انتشار: 1402/07/09
  • تعداد عناوین: 25
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  • T. Puspaningrum, N.S. Indrasti, C. Indrawanto, M. Yani * Pages 653-672
    BACKGROUND AND OBJECTIVES
    Coconuts and their derivatives, such as copra and charcoal, are leading commodities of Indonesia contributing to local consumption and exports. Life cycle assessment is a tool for evaluating the inputs, outputs, and potential impacts of a product system throughout its life cycle and is associated with product sustainability. The cradle-to-gate life cycle assessment of copra and coconut shell charcoal aims to determine the impacts of coconut, copra, and charcoal production from copra byproducts quantitatively and identify scenario improvements to reduce the impacts and enhance sustainability.
    METHODS
    Field observations were conducted in tall coconuts in Agrabinta, South Cianjur, and in copra and coconut shell charcoal factories in Sukabumi, West Java, Indonesia. The life cycle assessment method comprises the following four stages: goal and scope definition, inventory analysis, impact assessment, and interpretation. The scope of this study was based on land preparation, nurseries, planting, fertilization, harvesting of mature coconuts, transportation of mature coconuts, copra production, transportation of coconut shells, and charcoal production. Ten impacts were calculated using the Center of Environmental Science of Leiden University Impact Assessment baseline method with Simapro software.
    FINDINGS
    This study obtained ten impact categories, not only the global warming potential impact similar to most studies of perennial crop products in Indonesia. Normalization results showed that the category with enormous impacts on humans from coconut cultivation and copra processing activities had terrestrial ecotoxicity potential. The largest impact on charcoal production was on the human toxicity potential. Separated coconut factories from plantations have a high impact because of high fuel transportation. Four recommendation scenarios were formulated: 1) utilization of smoke from pyrolysis into liquid, 2) implementation of organic coconut cultivation practices, 3) integration of coconut plantations with copra and charcoal processing plants and processing smoke into liquid, and 4) combining scenarios 1, 2, and 3. In scenario 3, seven of ten impacts showed the lowest value among other scenarios. This scenario potentially decreases the impact from 68.35 to 99.62 percent. The human toxic potential of coconut shell charcoal decreased from 2.92 × 105 to 109.43 kilogram 1,4-dichlorobenzene equivalent, terrestrial ecotoxicity potential decreased from 59 to 19 kilogram 1,4-dichlorobenzene equivalent, and the global warming potential decreased from 1753.55 to 93.03 kilogram carbon dioxide equivalent.
    CONCLUSION
    Life cycle assessment can evaluate the impacts of copra and coconut shell charcoal from the coconut cultivation to the production stages. Opportunities for improvement can be identified from the interpretation and hotspots. Scenario analysis results showed the potential of developing integrated coconut agroindustry with coconut plantations, copra factories, and charcoal factories to produce liquid smoke in one location. This integration markedly reduces the impact due to the reduction of transportation fuel and emissions and the treatment of air pollution from pyrolysis.
    Keywords: Coconut shell charcoal, Copra, Life Cycle Assessment, Sustainability, Tall coconut, Toxicity
  • R.G. Sarmurzina, G.I. Boiko, B.K. Kenzhaliyev, U.S. Karabalin, N.P. Lyubchenko, P.V. Kenyaikin *, Zh.B. Ilmaliyev Pages 673-690
    BACKGROUND AND OBJECTIVES
    The reduction of fresh water deficit and water-related morbidity is the most important problem of the state’s national security. The effective treatment of natural water in industrialized areas from natural and anthropogenic pollutants is the main ecological task. Coagulation is one of the effective methods used to treat water chemically to purify it. Aluminum polyoxychlorides have gained popularity because of their advantages over coagulants—aluminum and iron sulfates. No production of aluminum polyoxychloride occurs in Kazakhstan despite the need for coagulants (the minimum need is assessed at about 11 thousand tons). The work is aimed at theoretical justification and experimental proof of a principally new approach to the development of aluminum polyoxychloride production technology based on activated aluminum alloys containing metal activators, such as gallium, indium , and tin from 0.5 to 5 percent weight. In addition, the goal is solving environmental issues associated with improving the drinking water quality and related to environmental pollution with wastewater.
    METHODS
    The microstructures, phase components, and elemental compositions of alloys and reaction products were studied by scanning electron microscopy/energy dispersive X-ray spectroscopy. The thermal effects of alloys were investigated usin thermogravimetry methods. Oil content in wastewater was determined by spectrophotometry. Oil particle dimensions and wastewater zero potentials were determined using electrophoretic light scattering method and residual turbidity by turbidimetry. Water quality assessment was included in the purified water analysis and comparison with the sanitary and epidemiological standards established for drinking water supply and wastewater intended for water discharge.
    FINDINGS
    The structures and compositions of activated aluminum alloy containing metal activators - gallium, indium, and tin - from 0.5 to 5 weight percent and aluminum polyoxychlorides based on it were studied using modern instrumental methods. The efficiency of the treatment of natural and oil-contaminated wastewater with aluminum polyoxychloride was assessed. The treated water parameters were within the norms established for drinking water supply and wastewater disposal by Sanitary Rules and Norms 2.1.4.559-96. The efficiency of potable water treatment reached 90–99 percent.
    CONCLUSION
    An effective and technologically simple method is developed for producing aluminum polyoxychloride. It involves dissolving an activated alloy in 1–5 percent hydrochloric acid, with an aluminum content of 98.5–85 percent. Alloy processing is carried out at temperatures ranging from 60 to 65 degree celsius. The temperature rises from 20 to 25 degree celsius to the specified optimum without heat supply from the outside due to the interaction among reagents. The process is completed in 2–3 hours. The results confirm that aluminum polyoxychloride is an effective coagulant for drinking and wastewater treatment. The treated water is within the established limits in terms of hydrogen potential, chemical oxygen demand, and turbidity. The water treatment method can be easily implemented.
    Keywords: Activated aluminum alloys, Aluminum polyoxychloride, Coagulant, Microstructure, Water treatment
  • E. Frimawaty *, A. Ilmika, N. Sakina, J. Mustabi Pages 691-706
    BACKGROUND AND OBJECTIVES
    Farmer characteristics are recognized in this study. The characteristics, perceptions, willingness to adopt climate change mitigation, and awareness of livestock farmers toward livestock waste management are the main points for determining appropriate climate mitigation rules.
    METHODS
    This study was conducted in Enrekang and Barru Regencies of South Sulawesi. International Business Machines - Statistical Package for the Social Sciences 27 was used for this study. In descriptive statistics, data were compiled, and the age, long husbandry experiences (year), number of family member, number of farming assistant, gender, education, farmer group participation status, side job, type of business, cattle ownership status, number of cattle (head), and weight total of cattle’s manure (kilogram per day) were examined qualitatively. A chi-square test was used to compare the experimental results (perception and knowledge of livestock manure management) with practical livestock manure management.
    FINDING
    This study found that the average age of farmers in the study area is 45 and 11.2 percent received have high formal education level from a university. Most of the cattle are male at 86.7 percent. Poor manure management system at 76.30 percent manure un-managed and un-appropriate farmer groups with more than 60 percent of the farmers un-joined farmer’s group. Almost 50 percent of the cattle farmers are willing to learn manure management. Nevertheless, this study found that the respondents’ knowledge and practical manure management, as well as the respondents’ knowledge (0.837) and perception (0.343) of practical manure management, do not have any significant connection.
    CONCLUSION
    This study determines the full condition of cattle farmers in Barru and Enrekang Regencies. Barriers include low level of education, age of farmers, lack of manure management, and lack of willingness to join farmers group. Nevertheless, drivers, such as willingness to adopt manure management and high levels of experience in cattle farming,  were also found. Enriching the knowledge and perception of farmers is essential in managing livestock wastes to mitigateof climate change.
    Keywords: Adaptation, Climate change, Livestock waste, Mitigation, Perception
  • S. Saneha, T. Pattamapitoon *, S. Bualert, O. Phewnil, W. Wararam, N. Semvimol, K. Chunkao, C. Tudsanaton, M. Srichomphu, U. Nachaiboon, O. Wongsrikaew, P. Wichittrakarn, C. Chanthasoon Pages 707-718
    BACKGROUND AND OBJECTIVES
    The bacterial community plays a crucial role in the nitrogen cycle. Oxidation ponds act as a natural treatment system for wastewater and are designed to promote the growth and activity of certain bacterial species that remove contaminants from the water. The nitrogen cycle in these ponds involves the conversion of nitrogen compounds through biological processes by bacteria. The presence or absence of certain bacterial species can greatly influence the efficiency of the nitrogen cycle in these ponds. This research investigates the relationship between bacteria and nitrogen dynamics, the key components of wastewater treatment, in oxidation ponds. This work aims to identify the bacterial community composition in oxidation ponds, investigate the role of bacteria in the transformation and removal of nitrogen compounds from wastewater in oxidation ponds, and evaluate the impact of environmental factors on the microbial communities and nitrogen dynamics in oxidation ponds. This study was carried out in the oxidation wastewater treatment at the King’s Royally Initiated Laem Phak Bia Environmental Research and Development or LERD Project, in Phetchaburi, Thailand.
    METHODS
    Wastewater samples were collected from the 1st–5th oxidation ponds at a depth of 30 centimeter from the water surface and analyzed for various quality parameters including temperature, dissolved oxygen, potential of hydrogen, biochemical oxygen demand, nitrates, ammonia, and total kjeldahl nitrogen. Next-generation sequencing by Illumina Miseq was used to examine the 16S ribosomal ribonucleic acid of bacteria in the collected samples. Correlation test was used for statistical analysis.
    FINDINGS
    The temperature, potential of hydrogen (1st to 5th ponds), and dissolved oxygen (2nd to 5th ponds) in the oxidation ponds were within the standard value. Fifteen bacterial phyla were identified in the five oxidation ponds, with phylum Proteobacteria accounting for the highest population comprising 47.56% of the total bacterial population.
    CONCLUSION
    Genera Novosphingobium (phylum Proteobacteria), Ammonia-11 (phylum Verrucomicrobiota), and Vicinamibacteraceae (phylum Acidobacteriota) have the strongest relationships with ammonia, nitrate, and total kjeldahl nitrogen (R2 = 0.9710, 0.986, 0.8124). The bacterial population is a crucial factor in nitrogen nutrient and water quality. Novosphingobium is involved in the removal of ammoniafrom wastewater, Verrucomicrobiota act as denitrifiers, and Vicinamibacteraceae increases the total kjeldahl nitrogen levels.
    Keywords: Bacterial Communities, Nitrogen, Nitrogen dynamic, Oxidation ponds, Wastewater treatment
  • A.M. Sabilillah, F.R. Palupi, B.K. Adji, A.P. Nugroho * Pages 719-740
    BACKGROUND AND OBJECTIVES
    The threat posed by microplastics to humans through fish consumption is potentially great due to microplastics’ capacity to adsorb heavy metals. The Code and Gajahwong streams have suffered from plastic and heavy metal pollution as the major rivers in Yogyakarta, Indonesia. However, little is known about the cumulative danger caused by the association of the microplastic and heavy metals. A thorough analysis of the extent of the health risks that people who consume fish from these rivers may experience is urgently needed. Hence, this study aimed to study microplastic pollution accumulated by fish in Code and Gajahwong streams, analyze the interactions with heavy metals, and assess the potential health risks.
    METHODS
    Fish sample collection was conducted in three stations by considering the severity of plastic pollution. Microplastics were extracted from the gills, digestive tract, muscle, and water and then characterized based on the number, size, shape, color, and type of polymer. Potential health risks were evaluated based on the potential ecological risk index, polymer hazard index, pollution load index, estimated daily intake, target hazard quotient, total target hazard quotient, and target cancer risk.
    FINDINGS
    Microplastics have contaminated the streams and fish and were dominated by small-sized green fibers and low-density polyethylene polymer. The pollution was related to human activities around the streams. The highest accumulation in fish was found in the digestive organs. Lead and cadmium have been associated with microplastics. The calculation of the potential ecological risk index and polymer hazard index showed that the medium risk of microplastic contamination in both streams. Based on the values of estimated daily intake, target hazard quotient, total target hazard quotient, and target cancer risk, short-term consumption of fish from the streams carries a low risk, but it will increase over time and pose a serious harm in the long term.
    CONCLUSION
    Given that most of the microplastics found were associated with lead and cadmium, they can increase the risk to human health due to the transfer of microplastics through food chains. Mitigation efforts involving various stakeholders, community involvement, and continuous education must be continuously pursued. This study significantly contributes to the current problem of environmental pollution by means of microplastic threats associated with heavy metals and provides a thorough health risk assessment applicable to other rivers and mitigation efforts that must be exerted to achieve sustainability.
    Keywords: Contamination, Fish, Health risk assessment, heavy metals, microplastics
  • D. Jaishree *, P.T. Ravichandran, D.V. Thattai Pages 741-752
    BACKGROUND AND OBJECTIVES
    Studying the monthly variations in the surface features of the Bay of Bengal is a complex task that involves numerous large-scale ocean-atmosphere dynamics. This study identified the bay’s changing circulation patterns over recent decades as a crucial study area requiring in-depth research. Understanding the changes in circulation patterns provides valuable insights into the Bay dynamics. It helps identify the potential impacts of climate change, ocean currents, and other factors on the bay’s ecosystem. This study aims to understand the seasonal variability of the Bay of Bengal’s surface circulation features using a high-resolution numerical Coastal and Regional Ocean Community simulations model.
    METHODS
    To conduct the study in the Bay of Bengal, the Coastal and Regional Ocean Community model, a numerical ocean model, was utilized. The high-resolution numerical model for ocean circulation is three-dimensional and uses hydrostatic primitive equations in generalized curvilinear coordinates. Simulations were conducted over 8 years using a grid comprising 256 x 249 horizontal surface points to model a range of ocean-atmospheric parameters. This grid provided an approximate resolution of 10 kilometers.
    FINDINGS
    The findings are based on the model’s enhanced performance compared to previous study results. It was observed that the sea surface temperature remains above 28 degrees Celsius throughout the bay except in winter. During the monsoon season, surface salinity was observed to be reduced in the Bay of Bengal’s northern region and western and eastern boundaries. Surface eddies along the western bay extend to deep waters before the onset of monsoon. The net heat flux in the bay has been determined as positive before monsoon, negative post-monsoon, and mixed during the monsoon season.
    CONCLUSION
    This analysis focuses on the ocean surface layer with more prominent dynamics. Various surface parameters were calculated, and discussions on surface temperature, salinity, D20, D26, and net heat flux across seasons have been presented.
    Keywords: Bay of Bengal (BoB), Coastal, Regional Ocean COmmunity model, Depth of the Isothermal Layer-D20, D26, Net heat flux, numerical model, Salinity, Temperature
  • L. Kasmini *, A.S. Batubara Pages 753-764
    BACKGROUND AND OBJECTIVES
    Oysters (Crassostrea gigas) are one food source commonly consumed by the community and an important commodity with high economic value. Environmental issues, such as microplastics, have become a worldwide concern for its implications for aquatic organisms, especially oysters. This study aims to identify the microplastics and growth patterns of oysters in Aceh Province, Indonesia's north and east coasts. This study aims to determine which oysters are suitable for consumption and food health based on research locations along the east-north coast of Aceh Province.
    METHODS
    The locations in this study include nine regencies/cities, which are directly facing the Malacca Straits. Microplastic isolation from oysters using 10 percent potassium hydroxide and incubation process were done to dissolve the organic materials. The growth pattern was analyzed to determine the growth rate of oysters at each study location.
    FINDINGS
    The results of this study showed that oysters in all sampling locations were contaminated with microplastics, with a high prevalence of 48 percent found in Langsa, followed by Aceh Timur and Pidie each (40 percent), Banda Aceh (38 percent), Aceh Utara (32 percent), Aceh Besar and Bireun (30 percent), Lhokseumawe (12 percent), and Aceh Tamiang (8 percent). The analysis of the growth patterns revealed that the growth of oysters at each location was not optimal (b <3 or negative allometric).
    CONCLUSION
    In 500 oyster samples collected, 139 were contaminated with microplastics. The most dominant type of microplastic contaminating oysters is fiber up to 170 particles, followed by films 28 particles, and fragments 19 particles. Negative allometric growth pattern might correlate with microplastics that contaminate the waters and enter the oyster's digestive organs. The results of this study reveal that oysters consumed by people have been contaminated with microplastics, so stakeholders must carry out socialization for early prevention to be realized.
    Keywords: Malacca, Prevalence, Alometric, Digestive
  • N. Fahimah *, I.R.S. Salami, K. Oginawati, S.J. Yapfrine, A. Supriatin, Y.N. Thaher Pages 765-788
    BACKGROUND AND OBJECTIVES
    Excessive presence of heavy metals in water sources can reduce water quality and harm human health. However, research on heavy metals from water sources for sanitation and hygiene purposes and drinking water in the Upper Citarum Watershed remains limited. This study focuses on the distribution of heavy metals and chemicals that have potential health risks.
    METHODS
    Ten heavy metals, namely, lead, cadmium, chromium, copper, cobalt, iron, mercury, manganese, arsenic, and zinc, were analyzed. Groundwater samples were collected from 160 locations, and drinking water samples (for respondents who do not drink groundwater) were collected from 98 locations. Heavy metal concentrations were detected using inductively coupled plasma optical emission spectrometry.
    FINDINGS
    The levels of arsenic, cadmium, cobalt, iron, mercury, manganese, and lead exceeded the quality standards for drinking water, while those of arsenic and cobalt did not exceed the quality standards for water hygiene and sanitation. Arsenic and cobalt quality standards were more stringent for drinking water compared with those for water hygiene and sanitation. Lead–cadmium and iron–manganese in groundwater showed a positive Spearman correlation (p<0.05) and may originate from the same source. Copper and zinc did not exceed the quality standard in 100% of drinking water samples. Iron and zinc in groundwater differed significantly due to variations in topography and soil type (p<0.05). This study reveals that 6 out of 10 heavy metals are chemicals of potential concern and are sorted based on potential risks to health, that is, arsenic > mercury > lead > cobalt > manganese > cadmium. Ingestion is the main pathway for potential risk, and children are more likely to be at risk than adults.
    CONCLUSION
    Stakeholders and decision makers must immediately implement sustainable actions to protect public health. Evaluation of water sources, technology, maintenance processes, and water quality should be conducted before and after technology use from Refill Drinking Water Depots to ensure that raw and processing water meets the quality standards.
    Keywords: Chemical of potential concerns (COPCs), Drinking water, Groundwater, Health risk, Hygiene, sanitation, Spatial distribution
  • S. Dhanasekar, R. Sathyanathan * Pages 789-804
    BACKGROUND AND OBJECTIVES
    Recent investigations indicated that continuous use of fertilizers and pesticides in agricultural fields not only deteriorated soil health but also caused a deleterious effect on surface and groundwater bodies. Treating such wastewater using microalgae has shown higher nutrient removal and biomass efficiency. Moreover, microalgae are proven to be miniature factories that augment the huge potential of biofuel. The aim of this study is to evaluate the different light intensities required for Chlorella vulgaris algae to remove nutrients from synthetic agricultural wastewater in a fabricated bubble column photobioreactor. Additionally, the research findings focus on assessing the degradation of organic pollutants and biomass generation under different light conditions.
    METHODS
    In this study, synthetic agrochemical wastewater was treated in a bubble column photobioreactor with blue, red, sunlight, and white light conditions. The treatment was conducted in a batch process with a hydraulic retention time of 21 days, using light intensity of 1800–2800 luminescence and a temperature maintained at 25–28° degrees Celsius.
    FINDINGS
    Under different lighting conditions, the blue light condition exhibited a higher biomass concentration of 3.99 gram per liter, with an estimated heat energy value of 1.278 kilojoule per liter. Moreover, in the blue light condition, scanning electron microscopy analysis showed no significant changes in the shape of Chlorella vulgaris and energy-dispersive X-ray analysis elemental composition exhibited the lowest oxygen-to-carbon ratio (1.03). Fourier transform infrared spectroscopy was used to illustrate the functional group of microalgae under different lighting conditions. The lipid, protein, carbohydrate, and amino acid contents were 3329–3332, 2116–2139, 1636–1645, and 545–662 per centimeter, respectively. The higher biomass potential from the wastewater treatment shows significant benefit in terms of feedstock and biofuel production.
    CONCLUSIONS
    The present investigation identified the nutrient reduction and biomass productivity to be more in blue light condition for Chlorella vulgaris algae. The investigation also assessed the potential of lipid, carbohydrate, and protein content in Chlorella vulgaris, which indirectly evaluates the biofuel potential of the species.
    Keywords: Bioenergy, Biological wastewater treatment, Chlorella vulgaris, Nutrient removal, photobioreactor, Phycoremediation
  • S. Ajbar El Gueriri, F. El Mansouri *, F. Achemlal, S. Lachaal, J. Brigui, A. Fakih Lanjri Pages 805-818
    BACKGROUND AND OBJECTIVES
    Good health and a safe environment are essential for sustainable development, including the appropriate management of healthcare wastes. The study intends to assess the generation rate and management methods of healthcare waste in the regional hospital center and a private clinic in Tangier, Morocco, with a focus on potential risks to health workers from infectious diseases.
    METHODS
    The study collected data on healthcare waste generation over a period of two months by measuring and analyzing general and hazardous waste using an electronic scale. The data was presented as averages in kilograms per bed per day and as percentages. A questionnaire was provided to 100 healthcare workers. It included questions on their sociodemographic characteristics and their knowledge and attitudes regarding healthcare waste management.
    FINDINGS
    The case study revealed that the healthcare waste production in the two institutions varied, with the private clinic producing 0.76 kilograms per day per bed and the regional hospital center producing 1.84 kilograms per day per bed. The survey also discovered that the hazardous fraction of waste generated in the regional hospital center was 40 percent, which was much higher than the World Health Organization’s estimation. The daily amount of hazardous waste generated increased from 260.49 kilograms to 436.81 kilograms post-COVID-19. The survey found gaps in knowledge, attitudes, and daily challenges in waste management practices among the health workers in both facilities.
    CONCLUSION
    The survey findings suggest that the healthcare waste management methods in Tangier are unsafe and may endanger the health workers and patients. The study found that the lack of monitoring and control contributed significantly to noncompliance with good practices. These findings can be used by the regional divisions of the Ministry of Health to develop specific protocols for managing sanitary emergencies and perform routine observation and training at all levels in the two facilities studied.
    Keywords: Covid-19 Pandemic, Hazardous Medical Waste, Healthcare waste, Health workers, Waste production
  • D. Pringgenies *, W. Ari Setyati, F. Feliatra, D. Ariyanto Pages 819-832
    BACKGROUND AND OBJECTIVES
    Mangroves are known to contain tannins, flavonoids, and quinones, which have the potential to be antibacterial, effective even against multidrug-resistant bacteria. Mangroves also have antifungal and antiviral properties. Although, mangroves are known for their use as medicinal ingredients, information regarding symbiont bacteria’s antibacterial and antifungal potential is still scarce. Therefore, this study aimed to examine symbiont bacteria in the fruit and leaves of Xylocarpus granatum as additional raw materials for anti-acne cosmetic creams and moisturisers.
    METHODS
    Symbiont bacteria were isolated using the pour plate method through Zobell 2216E and incubated for 2 x 24 hours at 27.5 Celcius degree. Afterwards, 13 isolates were successfully isolated and characterised based on their morphology. Further, everal tests were conducted, including the antibacterial test, antifungal test, molecular identification, and gas chromatography-mass spectrometry. The pathogenic bacteria used in the antibacterial test were Staphylococcus aureus, Vibrio harveyi, and Vibrio alginolyticus
    FINDINGS
    The antibacterial test results showed that eight isolates were capable of producing an inhibition zone against S. aureus, seven isolates were positive for antibacterial activity against Vibrio harveyi, and 10 isolates were positive for antibacterial activity against Vibrio alginolyticus. The pathogenic fungi used in the antifungal test were Malassezia furfur and Candida albicans. The antifungal test results demonstrated that six isolates could produce inhibition zones against Malassezia furfur and Candida albicans. Furthermore, molecular identification was carried out on six potential isolates based on the antibacterial and antifungal tests, which were X2.52, X1.65, X1.64, X1.53, X1.54, and X1.63. The molecular identification results revealed the occurrence of four species in the Xylocarpus granatum mangroves, namely, Sinomicrobium oceani, Proteus mirabilis, Pseudomonas khazarica, and Alcaligenes aquatilis.
    CONCLUSION
    The study found that the mangrove symbiont bacteria had antibacterial and antifungal potential. The compound with the highest concentration in six isolates was 9-octadecenoic acid, methyl ester. This type of content has antibacterial potential and is also predicted to have antifungal potential.
    Keywords: Bacteria, cosmetic, GC-MS, fungi, Pathogenic
  • K. Narozhnykh * Pages 833-850
    BACKGROUND AND OBJECTIVES
    Elemental status is associated with the biochemical processes occurring in the body. Beef, consumed worldwide, is an excellent source of iron in terms of quantity and bioavailability, providing up to 18 percent of the daily requirement. The level of iron in muscle tissue affects beef quality. Current methods used to assess iron content in cattle muscles are laborious and complex. Accordingly, the current study aimed to develop a fast and simple method to assess the elemental status of animals in vivo and in a minimally invasive way based on an effective model for iron-level prediction by using blood-analysis results toward ecological well-being. This method can overcome the shortcomings of currently used approaches.
    METHODS
    Samples of diaphragmatic muscle weighing 100 grams, as well as blood samples, were obtained from Hereford cattle bred under typical conditions of an industrial complex in the south of Western Siberia, Russia. Elemental analysis was performed by atomic absorption method with electrothermal atomization. Regression analysis was conducted to estimate the relationships between iron level in the muscle tissue of Hereford cattle and independent values (blood parameters). An optimum model for predicting the iron level was established. The coefficients of regression models were calculated using the least squares method, and the values of the dependent variable corresponded with the Gaussian ones. A high correlation existed between independent variables.
    FINDINGS
    An optimum model for predicting the iron level in the muscle tissue of Hereford cattle was established. It contained three predictors, namely, number of erythrocytes, color index, and globulin, as a result of selection based on internal and external-quality criteria. The model meets the necessary assumptions: the residuals are normally distributed, no autocorrelations exist, and the observations are influential. Furthermore, no signs of multicollinearity exist between the main effects of the model (variance-inflation factor = 1.2–1.7).
    CONCLUSION
    The model can be used for the intravital analysis of iron level in the muscle tissue of cattle. In contrast to currently used methods, the approach proposed can be used for intravital analysis of the level of iron in muscle tissue, which is the most important advantage of the developed approach. The results can be used in ecology to assess ecological well-being and determine the allowable load of iron in animals. For veterinary medicine, the resulting model enables the evaluation of the iron level in the muscle tissue of Hereford cattle during their lifetime. Studying the effect of different factors on meat quality may allow to decrease or avoid useless measures used in farming, such as the excessive use of feed additives. In turn, these measures can decrease resource exploitation and increase farming productivity. Therefore, the results can guide the further development of sustainable farming.
    Keywords: Cattle, Hereford breed, Iron, regression models
  • A.D. Santoso *, T. Handayani, R.A. Nugroho, A.I. Yanuar, N. Nadirah, E.S. Rohaeni, E. Widjaja, M.A.M. Oktaufik, U. Ayuningtyas, Y.P. Erlambang, R. Herdioso, M.N. Rofiq, R. Hutapea, A.L. Sihombing, B. Rustianto, I.M.A.D Susila, D. Irawan, D. Iskandar, S. Indrijarso, G.D. Widiarta Pages 851-870
    BACKGROUND AND OBJECTIVES
    Most food waste is dominated by domestic activities consisting of large numbers of organic pollutants, such as nitrogen and phosphate potentially hazardous to the environment. Domestic waste can be used as a feed source in black soldier fly cultivation with utility in pollutant removal, animal feed production, and compost fertilizer. Therefore, this study aimed to determine sustainability of larvae from black soldier fly cultivation by calculating and analyzing index.
    METHODS
    Data collection was conducted using the scientific judgment of experts and business actors in black soldier fly through Focus Group Discussion and the filling out of questionnaires consisting of 31 attributes connected with environment or ecology, economics, social, and technology dimensions. Furthermore, the data were calculated using the multi-dimensional scale approach with rapid appraisal software. Sustainability status and leverage attributes were analyzed by Monte Carlo analysis, and alternating least-squares algorithm.
    FINDINGS
    Sustainability index for larvae of black soldier fly production was 89.69 percent. The result suggested that the technique in several stages of operation including waste collection, cultivation, harvesting, and commercialization contributed to sustainability development when the elements of strength of each dimension are considered. From the analysis of the four dimensions, economic dimension had 100 percent or maximum leverage value. The environmental and social dimensions had the same leverage values of 92.02 percent, while the technological dimension had 74.74 percent. The results indicated that management experiences and techniques, potential for odor generated, family member involvement, productivity level, and managers level, warrant further attention to improve sustainability of black soldier fly production.
    CONCLUSION
    Production, productivity, land conversion, and population were identified as significant or dominating factors impacting the supply framework of black soldier fly production by the intended investigation inside the display ponders. Therefore, study should be encouraged to effectively integrate black soldier fly biomass as a value-added component in an ideal environmental, social, economic, and technical system. The results are significant in providing insights into the possibility of feasible black soldier fly biomass production in Indonesia, which can inform government policies and programs.
    Keywords: Black soldier fly (BSF), Food waste (FW), Multi-dimensional scaling (MDS), Sustainability
  • B. Parsafar, M. Ahmadi, Gh.R. Jahed Khaniki *, N. Shariatifar, A. Rahimi Foroushani Pages 871-884
    BACKGROUND AND OBJECTIVES
     Receiving nutrients from fruits and vegetables are essential for public health. However, a large amount of waste is produced during producing, supplying, and consuming these fruits and vegetables. Water, fertilizers and pesticides used for the production of agricultural products can affect the soil and their cultivation environment and finally lead to environmental pollution. Therefore, this study aimed to investigate the amount of fruit and vegetable waste caused by corruption and evaluate its economic loss and health damage.
    METHODS
    The data were collected using the observation technique aided by observation tools and weighing tests to physically analyze and determine the quantity and quality of waste from Tehran’s fruit and vegetable distribution centers. In each center, the waste obtained from fruits and vegetables was stored in special waste tanks at the end of the day, and the waste was transported to outside the center by special waste disposal vehicles. The economic loss of unusable fruits and vegetables was calculated according to the weight of their waste in the fields of agricultural product supply. The data were analyzed using statistical software SPSS, ANOVA statistical test, and Excel software.
    FINDINGS
    The results revealed that the amounts of fruit and vegetable wastes were 12 percent and 24 percent, respectively, accounting for a total loss of 54,891,539 USD. The highest quantity of fruit waste (15 percent) was observed in summer, and the economic loss due to fruit waste was higher in this season. Also, the amounts of vegetable waste in summer and spring were equal to 28 percent and 24 percent, respectively, indicating the higher economic loss due to vegetable in these seasons.
    CONCLUSION
    The results showed that the economic loss due to vegetable waste was greater than the economic loss due to fruit waste. The amount of vegetable waste was 24 percent, representing a high economic loss. The generation and disposal of these wastes caused a great economic loss and health problems due to their unpleasant odor, release of leachate into the environment, and landfill pollution. Therefore, it was recommended to follow appropriate production principles and supply operations. Moreover, a comprehensive waste disposal management, as a practical measure, should be used to prevent and control these problems. The use of modern technology in harvesting, transporting and supplying fruits and vegetables could reduce their lesion, and subsequently reduce the economic loss.
    Keywords: economic loss, Environmental waste management, Food waste, Fruits, vegetables disposal
  • L. Sulistyowati *, Y. Yolanda, N. Andareswari Pages 885-898
    BACKGROUND AND OBJECTIVES
    The Belawan Harbor is the third largest port, which is located in an estuary, causing the port water area to be vulnerable to pollution, especially heavy metals. Conflicts between the community and the port authorities often occur due to pollution. Heavy metals are dangerous contaminants for waters, and total organic carbon in waters is needed but will cause eutrophication if the concentration is excessive in the environment. The level of heavy metal pollution in the waters of the Belawan Harbor and the factors that cause the pollution should be analyzed, because the level of heavy metal pollution has not been measured in the sediments of harbor waters. This study can be used as a reference for the actions of related agencies in dealing with heavy metal pollution in waters.
    METHODS
    Sampling of sediments was performed at 10 locations, starting before the harbor activity began and moving toward the open sea. Sampling was conducted using Van Veen grab. Heavy metal concentrations were analyzed in the laboratory using the atomic absorption spectrometer method to assess the essential heavy metal copper and non-essential heavy metal lead, cadmium, and mercury. Heavy metal pollution in sediments was assessed by analyzing sediment pollution index. The multivariate statistical analysis on the relationship among factors was conducted using Pearson correlation matrix method, principal component analysis, and cluster analysis.
    FINDINGS
    The environmental quality standards used indicate average concentration of heavy metals; lead (28,869 milligram per kilogram) and copper (8,003 milligram per kilogram) are below the quality standard. The mercury concentrations are undetectable (<0.00011 milligram per kilogram) at each station. By comparison, the concentration of cadmium (1,455 milligram per kilogram) exceeded the Interim Sediment Quality Guidelines from the Canadian Council of Ministers of the Environment. Results of the index analysis show that the average value of the pollution factor of copper is −0.177 (low contamination), that of lead is −1.433 (moderate contamination), and that of cadmium is −4.850 (high contamination); the geoaccumulation index value of copper is −5.328. (not polluted), that of lead is −0.190 (unpolluted), and that of cadmium −1.657 (moderately polluted). As mercury concentration in sediments is relatively low, it is not considered when calculating pollution levels. Overall, on the basis of a pollution index of 1.033 (1 < pollution load index ≤ 2), this condition indicates that the waters of the Belawan Harbor are categorized as not polluted to lightly polluted. The highest total organic carbon is at the estuaries of the Belawan and Deli Rivers. The sediment fraction is 72.2 percent sandy, 16.4 percent sludge, and 11.4 percent clay substrate.
    CONCLUSION
    Pollution in the waters of the Belawan Harbor is in the category of not polluted to slightly polluted. Although the pollution is still in the light category, this must be of particular concern to the relevant agencies, especially the local government, to make the right policies to overcome this pollution immediately. Pollution problems increase with the anthropogenic activities around coastal areas, as well as activities in the Belawan and Deli River watersheds, because the pollutant will flow from the upstream to the estuary area.
    Keywords: Belawan Harbor, Heavy metal, Multivariate statistical analysis, Sediment pollution index, Total organic carbon (TOC)
  • M.H. Mansour * Pages 899-914
    BACKGROUND AND OBJECTIVES
    Despite the various environmental challenges the hotel sector faces, there is a significant need to resolve them by applying sustainable techniques like green human resource management. As a result, there is a pressing need to investigate how green human resource management may improve environmental performance. This study investigates the causal linkage among environmental awareness, green human resource management, green behaviours, green performance, and servant leadership.
    METHODS
    The data were collected via Questionnaires obtained from employees working in hotels in Amman, Jordan (52.5 per cent response rate). To evaluate the model, Smart Partial Least Square was employed to conduct validity and reliability testing and develop structural equation modeling.
    FINDINGS
    According to the results, Environmental awareness mediated the effects of green human resource management and green behaviours on green performance. Green HRM was found to have a direct and substantial impact on Green Performance (β = 0.109, p < 0.005). A positive and statistically significant relationship between Green Behaviors and Green Performance was also found (β = 0.338, p < 0.000). Additionally, Green HRM has a favorable and significant effect on Environmental Awareness (β = 0.176, p < 0.0001). Furthermore, Environmental Awareness is positively and significantly influenced by Green Behaviors (β = 0.743, p < 0.000). Green performance positively relates to environmental consciousness (β = 0.186, p < 0.000).
    CONCLUSION
    Based on social cognition, social exchange, and social learning theory, this study contains theoretical insights, practical implications, and positive recommendations for hospitality managers and scholars. Current research is critical because it emphasizes environmental stewardship in industries that directly connect to and influence the environment, such as tourism and hospitality. The study does not examine environmental performance and behavior in general but instead evaluates pro-environmental behaviors in depth by considering green behaviour.
    Keywords: Environmental awareness, green behaviors, Green human resource management (HRM), Partial Least Square Structural Equation (PLS-SEM)
  • F. Mardianti, D.E. Purba * Pages 915-932
    BACKGROUND AND OBJECTIVES
    In this era of globalization, clean water management is considered a complex problem requiring the strategic management of various aspects. Citizen participation in managing polluted waters is a critical, determining factor in preventing water crises. This study predicts the socioeconomic factors influencing citizens’ behaviors in polluted water management.
    METHOD
    A survey on Jakarta’s clean water was conducted with 503 respondents in 2022. Three interest variables were studied: first action taken during contamination, water nuisance level, and willingness to pay for clean water. Control variables were also explored, including daily income, education level, age, marital status, and gender. Data were analyzed using logistic regression.
    FINDINGS
    In general, socioeconomic factors influence citizens’ behaviors in dealing with polluted water. The specific findings regarding the probabilities for the first action on the basis of asking for immediate action from local authorities, namely, by asking other citizens, waiting for information from other citizens, and looking for sources of water pollution were –2.21, –3.50, and 0.61, respectively. The results also revealed the probabilities of nuisance level (0.07), willingness to pay for clean water (0.0495), daily income (–0.02), educational level (–0.429), and age (0.01). The probabilities for married citizens (–2.845) and men (–0.268) were lower than those for unmarried citizens and women, respectively.
    CONCLUSION
    The findings of this study can be used to predict the management of water pollution among Jakarta citizens, as well as serve as a reference for related stakeholders. Socioeconomic factors can affect citizens in various aspects of life, including participation in water management. However, not all socioeconomic factors are directly proportional to citizen participation. In fact, other socioeconomic indicators are inversely proportional to what are expected based on theoretical assumption. Finally, educational level and income do not always translate to behavioral changes linked to water pollution management.
    Keywords: citizen participation, Polluted water, socioeconomic, Urban water, Water Crisis
  • E. Ernyasih, A. Mallongi *, A. Daud, S. Palutturi, S. Stang, R. Thaha, E. Ibrahim, W. Al Madhoun Pages 933-950
    BACKGROUND AND OBJECTIVES
    The rising number of vehicles used for transportation, which is attributed to the steady increase in population, is known to be a major contributor of air pollution, which, in turn, can have adverse effects on the environment and human health. Therefore, in this study, we aimed to evaluate the concentration of carbon monoxide and fine particulate matter in the air and their potential health risks and further examine the use of probabilistic methods to simulate the sensitivity of people living in communities and school children to these pollutants.
    METHODS
    This study collected carbon monoxide and fine particulate matter samples from 32 stations near community houses and 14 sites near schools located along roads. Hazard quotient and target hazard quotient calculations were used to estimate the non-carcinogenic health risks associated with exposure to these substances for both community adults and school children. Finally, Monte Carlo simulations were applied to analyze the sensitivity and uncertainty risks.   
    FINDINGS
    As per the results, the highest level of carbon monoxide was recorded in station 22, with 6729 microgram per cubic meter, while the lowest was in station 24, with 1037 microgram per cubic meter. Station 10 had the highest concentration of fine particulate matter at 116 microgram per cubic meter, as opposed to station 2 with the lowest level at 10 microgram per cubic meter. In children, the hazard quotient value for carbon monoxide was found to be highest at 3.013, with the lowest at 0.614. Similarly, the highest level of target hazard quotient for carbon monoxide in children was 7.370, whereas the lowest was 1.522. For fine particulate matter, the highest risk level was 0.180. Additionally, the highest, and lowest levels of target hazard quotient for fine particulate matter were 0.311 and 0.037, respectively. Deterministic and probabilistic approaches were used to assess the risks these pollutants impose on adults and school children based on their daily inhalation rate. The results revealed that the 5th and 95th percentiles of cancer risk for carbon monoxide in adults were 2.85 and 6.11, respectively, indicating medium risks. However, for fine particulate matter, the 5th, and 95th percentiles were 0.09 and 0.19, respectively, signifying lower risks. For school children, the percentiles for carbon monoxide and fine particulate matter were 1.20 and 2.50, respectively, demonstrating higher risks.
    CONCLUSION
    As per the results, it was determined that the hazard quotient risk for carbon monoxide in adults exceeded the standard, >1, thus posing a risk. Only three stations had hazard quotient values lower than 1, which is deemed of safe level. Most of the fine particulate matter risk assessment results had hazard quotient values lower than 1, indicating a safe level. However, all other 30 stations had exceeded the World Health Organization standard (>1), thus demonstrating risks. The likelihood of the inhabitants being at risk increased as the frequency of discrete exposure occurrences increased; this is evidenced by target hazard quotient calculation results for both carbon monoxide and fine particulate matter at the 32 monitored station areas. These results warrant that future research should focus on reducing carbon monoxide and fine particulate matter in the environment by fostering awareness among local and national stakeholders as well as the academe; this may allow South Tangerang to become a center of excellence for green schools in the area.
    Keywords: Fine particulate matter (PM2.5), Health risk assessment, Carbon monoxide (CO), Monte Carlo Simulation, Sensitivity, Transportation activity
  • L.A. Omarbakiyev *, S.M. Kantarbayeva, A.K. Nizamdinova, S.T. Zhumasheva, G.Zh. Seitkhamzina, A. Saulembekova Pages 951-966
    BACKGROUND AND OBJECTIVES
    Geopolitical risks have made significant changes in the integration ties between the countries of Central Asia, which has affected the sustainable development of the agro-industrial complex and food security. The adoption of urgent measures to improve food security, on the one hand, is a necessary condition for the development of the Republic of Kazakhstan, but on the other hand, it can lead to a decrease in the level of environmental security in the country if the possible consequences in the reintegration process are not considered. Therefore, this article aimed to examine the sustainable agriculture practices implemented in Kazakhstan’s agro-industrial complex to improve food security and reduce the environmental impact of agriculture.
    METHODS
    To collect information, a mixed research strategy combining qualitative and quantitative methods was used. The collection of information was carried out in the summer of 2022 and consisted of three stages. In the first stage, statistical information was collected; in the second stage, a correlation analysis was carried out; and in the third stage, a survey of 40 experts was conducted.
    FINDING
    The data obtained indicate that the efficiency of Kazakhstan’s agricultural production strongly and directly depends on the level of the country’s integration into the united Eurasian Economic Union market. Due to the geographical features of Kazakhstan’s location, it is necessary to develop areas that are primarily focused on the internal capabilities of the country. Internal changes will help the industry increase international competitiveness and efficiency while promoting sustainable development and ensuring food security and environmental safety.
    CONCLUSION
    The article determined that it is necessary to prioritize developing multilateral partnerships to address transportation and logistics challenges in the export and import of agricultural products, and reduce dependence on the import of seeds, breeding products, fodder, and agricultural machinery. However, to effectively promote these areas, it is necessary to improve food security through the introduction of sustainable agriculture practices, such as crop diversification, conservation agriculture, integrated pest management, and drip irrigation.
    Keywords: Agricultural industry, Environmental Safety, Eurasian Economic Union market, Food Security, Partnership
  • D.P. Darmawan, G.M.K. Arisena *, A.A.A.W.S. Djelantik, A.A.K. Krisnandika, N.L.M.I.M. Dewi, N.T. Lukpitasari Korri, N.M.C. Sukendar Pages 967-982
    BACKGROUND AND OBJECTIVES
    The high need for tourism-supporting infrastructure has impacted the increasing conversion of land functions in Denpasar City, Indonesia. The lack of agricultural areas in Denpasar City has motivated farmers to continue farming. Farmer motivation to do farming will collide with obstacles in carrying out agricultural activities in Denpasar City. The purpose of this study was to examine the motivations and obstacles faced by farmers in carrying out agricultural activities. This research is relevant to the journal scope of Sustainable Agriculture Management, Urban, and Built Environmental Management.
    METHODS
    This study was carried out in Denpasar City in Indonesia, where each sub-district in Denpasar City will be selected by one Subak. The selection of Subak was based on the Subak with the most farmers in each sub-district in Denpasar City. The selected subak were Pakel 1 Subak, Kerdung Subak, Temaga Subak, and Margaya Subak. The population in this study was 672 people. The respondents in this study were 87 people. The data collection method was carried out using structured and in-depth interviews using questions and points while face-to-face between the interviewer and the respondent, via a prepared questionnaire. This study uses two variables with 41 indicators. The analytical methods used to point to objectives one, two, and three are descriptive quantitative and descriptive qualitative methods. Goal four is “Build a model for dealing with obstacles to farming in urban areas.” The fourth objective was analyzed descriptive qualitative based on the results of the analysis of objectives one, two, and three.
    FINDINGS
    The study results show that the motivation to continue farming is caused by demands to work, not having another job to get help from other parties, a healthy work environment, the ability to take lessons from previous farming experience affect product quality, and work in nature. The obstacles for farmers to continue farming are the bargaining position of farmers in selling products, market information obtained by farmers is still minimal, and market absorption of the products produced is not maximized.
    CONCLUSION
    Based on the results of the research, several things deserve to be concluded. The number of dependents of a farming family is more than six because there are still children of farmers already working but still being supported by their parents for their primary needs, and most of the farmers do farming in an area of 0.21 – 0.60 hectares. The motivation to keep farming is caused by the demands to work, not having another job to get help from other parties, a healthy work environment, and the ability to take lessons from the previous farming experience affecting product quality and work in nature. The obstacles for farmers to continue farming are the bargaining position of farmers in selling products, market information obtained by farmers is still minimal, and market absorption of the products produced is not maximized.
    Keywords: Agricultural, Farmers, Motivations, Obstacles, Urban areas
  • . Nurliza * Pages 983-994
    BACKGROUND AND OBJECTIVES
    Indonesia is the second largest natural rubber producer, which it gets primarily from smallholders. However, smallholders are less and less competitive because of unsustainable agricultural practices, while there is huge potential for sustainable natural rubber. This study aimed to measure the effect of income and smallholder characteristics on cultivation, harvesting, and post-harvest management.
    METHODS
    Mixed methods with non-probability sampling were used for 100 natural rubber smallholders in Kapuas Hulu Regency, West Kalimantan, Indonesia, one of the regional centers of Indonesian natural rubber. Partial least square path modeling was used with SmartPLS software to estimate the complex cause-effect relationships of smallholder and farm factors for adopting sustainable agricultural practices.
    FINDINGS
    The effect of the relationship between income and smallholder characteristics on cultivation and income on post-harvest management was not significant. Age and education affected some harvesting parameters, such as tapping knives, bamboo and clean latex collection, and latex stimulus risk, and some post-harvest parameters, such as a risk of acid coagulation and storage. The worker's income source, based on off-farm, on-farm, or non-farm activities, affected harvesting parameters, including tapping knives, bamboo and clean latex collection, and latex stimulus risk.  
    CONCLUSION
    This study offers empirical evidence for sustainable agriculture management. The acceptance of sustainable cultivation and management of rubber practices uses smallholder and farm factors as constraints since they do not form a homogenous group, and the theory of planned behavior failed to provide an effective way to explain the behaviors. Good agricultural practices must be used at all steps, including cultivation, harvesting, and post-harvest management, to prevent problems.
    Keywords: Farm factors, Farm management, Harvest, Natural rubber, Post-harvest, Smallholder factors, Sustainable agricultural practices
  • A. Abubakar, H. Yusuf *, M. Syukri, R. Nasution, M. Yusuf, R. Idroes Pages 995-1004
    BACKGROUND AND OBJECTIVES
    Medicinal plants growing in geothermal areas have been reported to possess relatively high concentrations of bioactive secondary metabolites, which have been attributed to the adaptive heat stress response. Nonetheless, the exploitation of their medicinal benefits is limited by potentially life-threatening concentrations of heavy metals. Chromolaena odorata Linn, also called seurapoh, is a well-known medicinal plant that can absorb and accumulate heavy metals from the soil. This present study aimed to investigate the contents of mercury, lead, cadmium, and arsenic in the ethanolic extract of Chromolaena odorata Linn leaves collected from a geothermal area in Aceh Province, Indonesia.
    METHODS
    Three hot springs, namely Ie-Suum, Ie-Jue, and Ie-Brouk, located in the same geothermal area, Seulawah Agam, were selected as the sampling points, and three samples of Chromolaena odorata were collected at each point. Extraction was carried out by means of maceration employing ethanol solvent. The heavy metal contents of each extract were determined using priorly validated atomic absorption spectrometry and graphite furnace atomic absorption spectrometry. The maximum thresholds of each heavy metal from the Indonesian Agency for Drug and Food Control were adopted during data interpretation.
    FINDINGS
    The results revealed the presence of trace levels of arsenic (0.0482 ± 0.004 – 0.0639 ± 0.007 milligram per kilogram) and lead (0.0219 ± 0.004 – 0.0672 ± 0.006 milligram per kilogram), which did not exceed Indonesian maximum safety thresholds (≤5 and ≤10 milligram per kilogram, respectively). Mercury in all samples was not observable (limit of detection = 0.018 milligram per liter). Cadmium was observed in almost all samples with a concentration range of 0.0219 ± 0.005–1.1472 ± 0.006 milligram per kilogram, which exceeded the maximum threshold (0.3 milligram per liter).
    CONCLUSION
    Heavy metal contamination in the ethanolic extract of geothermal Chromolaena odorata leaves has been attributed to volcanic activities. Among the heavy metals of concern, cadmium was the only one with a concentration exceeding the safety limit. The presence of cadmium in the extract at a high concentration could cause its translocation to the human body, eventually leading to multiple organ damage. Therefore, the extract of Chromolaena odorata leaves collected from a geothermal area should be consumed with caution for possible cadmium intoxication.
    Keywords: accumulator, Arsenic (As), Cadmium (Cd), Hot Spring, Lead (Pb), Mercury (Hg)
  • D.B. Aviantara, F. Suciati, G. Hadiko, N.S. Indrasti, M. Yani * Pages 1005-1018
    BACKGROUND AND OBJECTIVES
    Polychlorinated biphenyls are pervasive contaminants that are receiving attention worldwide. Due to their well-known propensity to have harmful impacts on both humans and the environment, polychlorinated biphenyls have been internationally banned for use. In this study, dechlorination of five polychlorinated biphenyl congeners, 2,2′,5,5′-tetrachlorobiphenyl, 2,2′,4,5,5′-pentachlorobiphenyl, 2,2′,3,4,4′,5′-hexachlorobiphenyl, 2,2′,3,4,4′,5′-hexachlorobiphenyl, 2,2′,4,4′,5,5′-hexachlorobiphenyl, and 2,2′,3,4,4′,5,5′-heptachlorobiphenyl, are evaluated. The chlorines from polychlorinated biphenyl congeners were removed using a heterogeneous catalyst synthesized via microwave-assisted impregnation of zinc metal onto pulverized shrimp shell waste.
    METHODS
    The five polychlorinated biphenyl congeners were dechlorinated through treatments combination of time (1–4 hours), heat (150–250 degree celsius), and catalyst proportion (1–5 percent weight/weight basis). The dechlorination trials followed the Box–Behnken experimental design and then analyzed using response surface methodology. Levels of the remaining polychlorinated biphenyl congeners were monitored by using a gas chromatograph equipped with an electron capture detector.
    FINDINGS
    The results of the trials demonstrated that among the five polychlorinated biphenyl congeners, only 2,2′,3,4,4′,5,5′-heptachlorobiphenyl did not respond to the provided treatments. Three congeners, namely, 2,2′,5,5′-tetrachlorobiphenyl, 2,2′,4,5,5′-pentachlorobiphenyl, and 2,2′,4,4′,5,5′-hexachlorobiphenyl, showed positive response, and one congener 2,2′,3,4,4′,5′-hexachlorobiphenyl showed negative response to the provided treatments. These findings suggested that chlorine attached to the para position of the biphenyls ring was easier to remove. The efficiency calculation of total polychlorinated biphenyl concentrations after treatments was approximately 25 percent. Such a low degree of effectiveness may be caused by the catalyst becoming inactive, either chemically through the deposition of chlorines that have been removed from the biphenyl ring or mechanically by the leaching of zinc from the surface of the pulverized shrimp shell due to insufficient mechanical strength. Optimization via response surface methodology produced optimal results for dechlorination at 150 degree celcius for 2.4 hours with 5 percent additional catalyst.
    CONCLUSION
    The total amount of polychlorinated biphenyls that remained after dechlorination was not significantly impacted by the treatment combination of temperature, duration, and weight of the catalyst. However, the treatments had significant effects on the chlorine removal at the para positions of the biphenyl ring. In this case 2,2′,5,5′-tetrachlorobiphenyl, 2,2′,4,5,5′-pentachlorobiphenyl, and 2,2′,4,4′,5,5′-hexachlorobiphenyl congeners have positive responses and 2,2′,3,4,4′,5′-hexachlorobiphenyl congener has a negative response. For polychlorinated biphenyl congeners having more than six chlorines, no chlorine removal was observed.
    Keywords: catalyst, Congener, Dechlorination, heterogeneous, Polychlorinated biphenyls
  • L. Sulistyowati *, N. Andareswari, F. Afrianto, A. Rais, M.F. Hafa, D. Darwiyati, A.L. Ginting Pages 1019-1032
    BACKGROUND AND OBJECTIVES
    The monitoring of the Brantas watershed showed a light-polluted status. This study began by identifying the priority of regional problems using importance-performance analysis. Furthermore, a hydrological analysis was conducted to determine the pollutant area of the Brantas watershed by applying terrain analysis. When terrain analysis in hydrology is combined with participatory community information, it can provide valuable insights into water pollution and help prioritize remediation efforts. Integrating local knowledge with scientific data can improve decision-making and increase the effectiveness of water management strategies.
    METHODS
    The methodological approach employed in this study included importance-performance analysis to determine priority problems in Batu City and terrain analysis as a hydrological analysis to determine the pollutant area in the Brantas watershed. The importance-performance analysis assessment data were obtained from 197 respondents representing the occupations of the people of Batu City. The terrain analysis data were derived from the surface elevation data in the form of a digital elevation model.
    FINDINGS
    According to the importance-performance analysis community assessment, urban trash management was one of the crucial yet low-rated features. The terrain analysis results demonstrated that business and industrial activities were distributed in locations with high flow accumulation values, indicating that the water pollution in Batu City was triggered by the presence of business and industrial activities in the watershed accumulation areas. Along the upstream Brantas watershed, 460 business and industrial activities were discovered. Therefore, the results of importance-performance analysis and terrain analysis had a correlation. They were also closely related to the assessment results of the contaminated Brantas watershed.
    CONCLUSION
    The following are some recommendations for the watershed's quality improvement: 1) cooperation among the Government, communities, and the private sector for addressing water pollution issues; 2) the development of environmentally friendly technologies in water treatment; and 3) education and outreach to communities about the importance of preserving water resources. As a city experiencing rapid urban development, environmental degradation constitutes a risk to be borne. Accordingly, Batu City must continue to develop good environmental management for the sake of nature conservation because the urban system is a unit formed by the social economy and ecological environment subsystem.
    Keywords: Community, Degradation, hydrology, Management, Strategy, Waste
  • F.G. Arredondo Trapero, E.M. Guerra Leal, J. Kim * Pages 1033-1048
    BACKGROUND AND OBJECTIVES
    Although governments and companies have been implementing various measures, such as technological innovation, new emissions regulations, and policies to reduce greenhouse gas emissions, it seems that global warming is not decreasing. In order to reduce greenhouse gas emissions, the commitments of companies were considered to be the key for climate change. However, since the Paris Climate Agreement, there has not been an accurate evaluation of the efforts and contributions of companies toward emission reductions. This study investigated the effectiveness of companies in Climate Action and tested its impact on greenhouse gas emissions at the country and per capita levels.
    METHODS
    This study focuses on companies of the countries from the main Latin American economies (Mexico, Chile, Brazil, Colombia, and Argentina) and their major trading partners (the United States of America, Canada, China, Korea, Germany, and Japan). There are 894 companies from Latin America and 3680 companies that represent their trading partners of referred countries in Climate Action. This study used two data sources, the commitment of companies from Global Climate Action and the annual greenhouse gas emissions levels of each country from an open-access data platform called Our World in Data.
    FINDING
    The findings demonstrate a significant and positive relationship between changes in greenhouse gas emissions from 2021 and 2020 and the number of companies participating in Global Climate Action (Pearson = .718*, significance = .013) and per capita (Pearson = 0.827** significance = 0.002). Correlations indicate there is a higher level of commitment to climate action but with marginal contributions to greenhouse gas emissions reduction. Previous expectations were that greater corporate involvement in climate action would reflect a link to greenhouse gas reductions, but this was not the case. Additionally, the reduction in greenhouse gas emissions during the pandemic was due to the economic slowdown and was not necessarily because of the climate action efforts of companies and governments to reduce emissions. The findings demonstrated a negative and significant correlation at the country level during the pandemic (Pearson = −0.629 significance = .038). The lack of effective results for reducing (from 2020 and 2021) greenhouse gas emissions justifies the relevance of increasing transparency and accountability for both companies and countries. The acceleration of the production system reflected in an increase in greenhouse gas emissions is not keeping pace with the commitments and the reported achievements on Global Climate Action.
    CONCLUSION
    This study contributed to justifying efforts for a better way to follow up international efforts to reduce greenhouse gas emissions. Transparency and accountability are key to effectively achieving greenhouse gas reductions and curbing the impending climate crisis.
    Keywords: Climate Action, Transparency, Greenhouse gasses, Latin America, Sustainable Development Goals (SDGs)